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624-48-6 - Dimethyl maleate, 96% - Maleic acid dimethyl ester - cis-Propenoic acid dimethyl ester - A18944 - Alfa Aesar

A18944 Dimethyl maleate, 96%

Codice CAS
624-48-6
Sinonimi
Maleic acid dimethyl ester
cis-Propenoic acid dimethyl ester

Dimensioni Prezzo ($) Quantità Disponibilità
100g 21,01
250g 32,03
1000g 90,00
5000g 342,40
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Dimethyl maleate, 96%

MDL
MFCD00008459
EINECS
210-848-5

Proprietà chimiche

Formula
C6H8O4
Peso formula
144.13
Punto di fusione
-19°
Punto di ebollizione
204-205°
Punto di infiammabilità
91°(195°F)
Densità
1.151
Indice di rifrazione
1.4420
Solubilità
Miscible with water.

Applicazioni

Dimethyl maleate is acts as a dienophile involved in ultrasonic irradiation promoted Diels-Alder reaction with substituted furans. It is widely used as an intermediate and additive for pharmaceuticals, copolymers, pigments, plastics, paints, adhesives and agrochemicals. As an internal modifier, it increases the glass transition temperature of styrene or vinyl chloride polymer. It plays a vital role to improve the hardness and toughness of polymer films such as copolymers of vinyl acetate.

Note

Incompatible with acids, bases, oxidizing agents and reducing agents.

Letteratura

Reactive dienophile. For a study of thermal cycloadditions with alkenes, see: J. Org. Chem., 57, 594 (1992).

Bosica, G.; Debono, A. J. Uncatalyzed, green aza-Michael addition of amines to dimethyl maleate. Tetrahedron 2014, 70 (37), 6607-6612.

Behr, A.; Toepell, S.; Harmuth, S. Cross-metathesis of methyl 10-undecenoate with dimethyl maleate: an efficient protocol with nearly quantitative yields. RSC Adv. 2014, 4 (31), 16320-16326.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H311-H302-H315-H335-H318-H227

Toxic in contact with skin. Harmful if swallowed. Causes skin irritation. May cause respiratory irritation. Causes serious eye damage. Combustible liquid.

Dichiarazioni precauzionali: P210-P261-P280-P305+P351+P338-P361-P304+P340-P310-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
471705
Classe di rischio
6.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2917.19
TSCA
Yes
RTECS
EM6300000

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