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Diallylamine is used as an intermediate for ion exchange resins, pharmaceuticals, water soluble polymers, rubber chemicals, polymerization initiators and cross-linking agents.
Florence Garro-Helion; Ahmed Merzouk; Francois Guibe. Mild and selective palladium(0)-catalyzed deallylation of allylic amines. Allylamine and diallylamine as very convenient ammonia equivalents for the synthesis of primary amines. J. Org. Chem., 1993, 58 (22), 6109-6113.
Susumu Harada; and Masamichi Katayama. The cyclo-copolymerization of diallyl compound and sulfur dioxide. I. Diallylamine hydrochloride and sulfur dioxide. Journal of Bacteriology, 1966, 90(1), 177-186.
Pd catalyzed coupling with aryl or heteroaryl halides followed by cleavage with methanesulfonic acid or BF3 etherate in the presence of Pd on carbon, provides a mild route to aryl or heteroaryl amines in which the diallylamine behaves as an ammonia equivalent: Tetrahedron Lett., 39, 1313 (1998).
Dichiarazioni di rischio (UE): H225-H302-H311-H330-H314-H318
Highly flammable liquid and vapour. Harmful if swallowed. Toxic in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Dichiarazioni precauzionali: P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.