Accetto Utilizziamo cookies per migliorare il nostro servizio e realizzare statistiche. Questa funzione puó essere disattivata cambiando la configurazione del browser. Continuando a navigare senza modificare questi parametri, consideriamo che l’uso di cookies sia accettato
Trimethyl borate is a useful reagent in organic synthesis. It is involved in the production of resins, waxes and paints and acts as a methylation agent. As a boron source, it is used to prepare flame retardants, anti-oxidants and corrosion inhibitors. It reacts with Grignard reagents followed by hydrolysis to prepare boronic acid. It is also used as a precursor of borate esters, which finds application in Suzuki coupling reaction. It is an intermediate in the preparation of sodium borohydride.
For an example of the low temperature reaction with Grignard reagents to give boronic acids., see: Org. Synth. Coll., 4, 68 (1963).
Bao, Z.; Zhang, W.; Cui, X.; Xu, J. Design, Optimization and Control of Extractive Distillation for the Separation of Trimethyl Borate-Methanol. Ind. Eng. Chem. Res. 2014, 53 (38), 14802-14814.
Chang, C. C.; Lee, K. Y.; Lee, H. Y.; Su, Y. H.; Her, L. J. Trimethyl borate and triphenyl borate as electrolyte additives for LiFePO4 cathode with enhanced high temperature performance. J. Power Sources 2012, 217, 524-529.
Dichiarazioni di rischio (UE): H225-H312
Highly flammable liquid and vapour. Harmful in contact with skin.
Dichiarazioni precauzionali: P210-P280-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.