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Sodium trifluoromethanesulfonate is used in the preparation of N-fluoro-2-methylpyridinium triflate by reaction with dinitrogen difluoride as a reagent. It is also used as a chaotropic mobile phase additive in reversed-phase liquid chromatography (RP-LC).
Sulfinylation of aromatic compounds can be brought about in triflic acid at room temperature to give good yields of aryl trifluoromethyl sulfoxides: Synlett, 550 (2001).
Catalyzes the aza Diels-Alder reaction of Danishefsky's diene (1-Methoxy-3-trimethylsiloxy-1,3-butadiene, L14672) with imines in water under neutral conditions: Chem. Commun., 574 (2003).
Lima, F. S.; Cuccovia, I. M.; Buchner, R.; Antunes, F. E.; Lindman, B.; Miguel, M. G.; Horinek, D.; Chaimovich, H. Sodium Triflate Decreases Interaggregate Repulsion and Induces Phase Separation in Cationic Micelles. Langmuir 2015, 31 (9), 2609-2614.
Ji, X. M.; Wei, L.; Chen, F.; Tang, R. Y. Direct trifluoromethylation of imidazoheterocycles in a recyclable medium at room temperature. RSC Adv. 2015, 5 (38), 29766-29773.
Dichiarazioni di rischio (UE): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.