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5324-30-1 - Diethyl 2-bromoethylphosphonate, 97% - 2-Bromoethylphosphonic acid diethyl ester - Diethyl 2-bromoethanephosphonate - B21156 - Alfa Aesar

B21156 Diethyl 2-bromoethylphosphonate, 97%

Codice CAS
5324-30-1
Sinonimi
2-Bromoethylphosphonic acid diethyl ester
Diethyl 2-bromoethanephosphonate

Dimensioni Prezzo ($) Quantità Disponibilità
5g 35,10
25g 133,00
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Diethyl 2-bromoethylphosphonate, 97%

MDL
MFCD00000239
EINECS
226-193-3

Proprietà chimiche

Formula
C6H14BrO3P
Peso formula
245.06
Punto di ebollizione
98-100°/1mm
Punto di infiammabilità
>110°(230°F)
Densità
1.275
Indice di rifrazione
1.4605
Solubilità
Soluble in water(20 g/L) (25°C).

Applicazioni

It is employed as a reactant involved in radical coupling, synthesis of organosoluble zirconium phosphonate nanocomposites, click-chemistry, asymmetric epoxidation of unfunctionalized olefins, Negishi alkyl-aryl cross-coupling, and in synthesis of hydrolytically stable phosphonic acids for use as dental adhesives.

Note

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Letteratura

Taotao Chen, et al. Organosoluble zirconium phosphonate nanocomposites and their supported chiral ruthenium catalysts: the first example of homogenization of inorganic-supported catalyst in asymmetric hydrogenation.Dalton Trans.201140(13), 3325-3335.

A. H. Ford-Moore and J. Howarth Williams. The reaction between trialkyl phosphites and alkyl halides.J. Chem. Soc.,19471465-1467.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P260-P201-P280g-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
1766077
Codice tariffe armonizzato
2931.39
TSCA
No

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