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1609-47-8 - Diethyl dicarbonate, 97% - Diethyl oxydiformate - Diethyl pyrocarbonate - B22753 - Alfa Aesar

B22753 Diethyl dicarbonate, 97%

Codice CAS
1609-47-8
Sinonimi
Diethyl oxydiformate
Diethyl pyrocarbonate

Dimensioni Prezzo ($) Quantità Disponibilità
5g 22,77
25g 67,14
100g 216,00
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Diethyl dicarbonate, 97%

MDL
MFCD00009106
EINECS
216-542-8

Proprietà chimiche

Formula
C6H10O5
Peso formula
162.14
Punto di ebollizione
93-94°/18mm
Punto di infiammabilità
69°(156°F)
Densità
1.101
Indice di rifrazione
1.3980
Sensibilità
Moisture Sensitive
Solubilità
Miscible with chloroform, ethanol, esters, ketones and hydrocarbons. Slightly miscible with water.

Applicazioni

Ribonuclease inhibitorDiethyl dicarbonate acts as an inhibitor of ryanodine binding to ryanodine/calcium(II) receptor channel. It is useful for specific inactivation of nucleases during isolation of undegraded polynucleotides. Further, it inhibits platelet-activating factor acetyl hydrolase. In addition to this, it is involved in the modification reagent for His and Tyr residues in proteins.

Note

Store in cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids, strong bases and ammonia.

Letteratura

In the presence of the hindered base lithium dicyclohexylamide (from Dicyclohexyl­amine, A15671), ɑ -ethoxycarbonylation of ketones occurs to give ß -keto esters: Synthesis, 1014 (1984).

Dogandzhiyski, P.; Ghidini, A.; Danneberg, F.; Stro?mberg, R.; Go?bel, M. W. Studies on Tris(2-aminobenzimidazole)-PNA Based Artificial Nucleases: A Comparison of Two Analytical Techniques. Bioconjugate Chem. 2015, 26 (12), 2514-2519.

Zuldesmi, M.; Waki, A.; Kuroda, K.; Okido, M. Hydrothermal treatment of titanium alloys for the enhancement of osteoconductivity. Mater. Sci. Eng., C 2015, 49, 430-435.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H302-H315-H319-H335-H227

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Dichiarazioni precauzionali: P210-P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,7998
Beilstein
637031
Codice tariffe armonizzato
2920.90
TSCA
Yes
RTECS
LQ9350000

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