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B22753 Diethyl dicarbonate, 97%

Codice CAS
1609-47-8
Sinonimi
Diethyl oxydiformate
Diethyl pyrocarbonate

Stock No. Dimensioni Prezzo ($) Quantità Disponibilità
B22753-06 5g 25,80
B22753-14 25g 72,60
B22753-22 100g 247,00
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Diethyl dicarbonate, 97%

MDL
MFCD00009106
EINECS
216-542-8

Proprietà chimiche

Formula
C6H10O5
Peso formula
162.14
Punto di ebollizione
93-94°/18mm
Punto di infiammabilità
69°(156°F)
Densità
1.101
Indice di rifrazione
1.3980
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Store under Nitrogen.
Solubilità
Miscible with chloroform, ethanol, esters, ketones and hydrocarbons. Slightly miscible with water.

Applicazioni

Ribonuclease inhibitorDiethyl dicarbonate acts as an inhibitor of ryanodine binding to ryanodine/calcium(II) receptor channel. It is useful for specific inactivation of nucleases during isolation of undegraded polynucleotides. Further, it inhibits platelet-activating factor acetyl hydrolase. In addition to this, it is involved in the modification reagent for His and Tyr residues in proteins.

Note

Store in cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids, strong bases and ammonia.

Letteratura

In the presence of the hindered base lithium dicyclohexylamide (from Dicyclohexyl­amine, A15671), ɑ -ethoxycarbonylation of ketones occurs to give ß -keto esters: Synthesis, 1014 (1984).

Dogandzhiyski, P.; Ghidini, A.; Danneberg, F.; Stro?mberg, R.; Go?bel, M. W. Studies on Tris(2-aminobenzimidazole)-PNA Based Artificial Nucleases: A Comparison of Two Analytical Techniques. Bioconjugate Chem. 2015, 26 (12), 2514-2519.

Zuldesmi, M.; Waki, A.; Kuroda, K.; Okido, M. Hydrothermal treatment of titanium alloys for the enhancement of osteoconductivity. Mater. Sci. Eng., C 2015, 49, 430-435.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H227-H302-H315-H319-H335

Combustible liquid. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P210u-P261-P280a-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,7998
Beilstein
637031
Codice tariffe armonizzato
2920.90
TSCA
Yes
RTECS
LQ9350000

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