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82-86-0 - Acenaphthenequinone, 95% - B23466 - Alfa Aesar

B23466 Acenaphthenequinone, 95%

Codice CAS
82-86-0
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 22,40
25g 47,90
100g 146,00
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Acenaphthenequinone, 95%

MDL
MFCD00003805
EINECS
201-441-3

Proprietà chimiche

Formula
C12H6O2
Peso formula
182.18
Punto di fusione
253-262°
Solubilità
Soluble in chloroform and alcohol. Insoluble in water.

Applicazioni

Acenaphthenequinone is used in the preparation of acetylcholinesterase inhibitory agents. It is also used in the preparation of turn-on sensors for cysteine/homocysteine and its application in bioimaging. Further, it is used as an intermediate in manufacturing of dyes and pharmaceuticals. In addition to this, it is used in chemical research as a drug and therapeutic agent.

Note

Incompatible with strong oxidizing agents.

Letteratura

Starting material for a three-step synthesis of corannulene: J. Am. Chem. Soc., 119, 10963 (1997), and also of a new C32H12 bowl-shaped aromatic hydrocarbon: Tetrahedron Lett., 38, 741 (1997).

Lin, Y.; Fu, Z.; Shen, T.; Che, F.; Song, Q. Efficient Protocol for the Synthesis of Novel Spiro[acenaphthylene-1,2'-pyrrolidin]-2-one Compounds. Synth. Commun. 2015, 45 (19), 2188-2194.

Batanero, B.; Ramirez-Moreno, M.; Barba, F. Electroinduced Carbene Formation in the Cathodic Reduction of 1,2-Dicarbonyl Compounds via Electron-Transfer to the Solvent. Electrochim. Acta 2015, 167, 207-212.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
879172
Codice tariffe armonizzato
2914.69
TSCA
Yes
RTECS
AB1024500

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