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77377-52-7 - N-(tert-Butyldimethylsilyl)-N-methyltrifluoroacetamide, 97% - MTBSTFA - TBSTFA - B23760 - Alfa Aesar

B23760 N-(tert-Butyldimethylsilyl)-N-methyltrifluoroacetamide, 97%

Codice CAS
77377-52-7
Sinonimi
MTBSTFA
TBSTFA

Dimensioni Prezzo ($) Quantità Disponibilità
1g 30,40
5g 98,90
25g 379,00
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N-(tert-Butyldimethylsilyl)-N-methyltrifluoroacetamide, 97%

MDL
MFCD00009671
EINECS
000-000-0

Proprietà chimiche

Formula
C9H18F3NOSi
Peso formula
241.33
Punto di ebollizione
168-170°
Punto di infiammabilità
52°(125°F)
Densità
1.023
Indice di rifrazione
1.4020
Sensibilità
Moisture Sensitive
Solubilità
Soluble in water (reacts).

Applicazioni

It finds its application in the preparation of N-tert-butyldimethylsilyl ethanolamines resulting from hydrolysis of nitrogen mustards and a silylating agent used in the derivatization of various organic compounds (such as amino acids) for gas chromatography-mass spectrometry (GC-MS) analysis and selective O-silylation of N,O-diacylhydroxylamines and GLC derivatization.

Note

Moisture sensitive. Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store away from electrostatic charges. Keep ignition sources away.

Letteratura

Ali Shareef, et al. Optimization of silylation using N-methyl-N-(trimethylsilyl)-trifluoroacetamide, N,O-bis-(trimethylsilyl)-trifluoroacetamide and N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide for the determination of the estrogens estrone and 17α-ethinylestradiol by gas chromatography-mass spectrometry.J. Chromatogr. A.,2006,1108(1), 121-128.

A. Royer, et al. Determination of ethephon residues in water by gas chromatography with cubic mass spectrometry after ion-exchange purification and derivatisation with N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide.J. Chromatogr. A.,2006,1108(1), 129-135.

Reactive silylating agent effective in acetonitrile for introduction of the TBDMS group with alcohols, thiols, amines, amides, carboxylic acids, as well as conversion of enolizable carbonyl groups to silyl enol ethers: J. Org. Chem., 47, 3336 (1982). See Appendix 4.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
3606546
Classe di rischio
3
Gruppo di imballaggio
III
Codice tariffe armonizzato
2931.90
TSCA
No

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