It is used in Suzuki reaction for generalized route for the synthesis of β-furyl-α,β-unsaturated aldehydes.
Michael J. Burns, et al. Simple Palladium(II) Precatalyst for Suzuki-Miyaura Couplings:? Efficient Reactions of Benzylic, Aryl, Heteroaryl, and Vinyl Coupling Partners.Org. Lett.,2007,9(26), 5397-5400.
Khokan Samanta, et al. A generalized route for the synthesis of β-furyl-α,β-unsaturated aldehydes through Suzuki reactions.Tetrahedron Lett.,2008,49(9), 1461-1464.
Undergoes an asymmetric boronic acid Mannich reaction with aldehydes in the presence of the chiral template (S)-5-phenylmorpholine-2-one to give substituted furfurylamines with high diastereomeric excess: Chem. Commun., 1953 (1996); J. Chem. Soc., Perkin 1, 2982 (2000):
Dichiarazioni di rischio (UE): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.