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87199-17-5 - 4-Formylbenzeneboronic acid, 97% - 4-Boronobenzaldehyde - 4-Formylphenylboronic acid - B25199 - Alfa Aesar

B25199 4-Formylbenzeneboronic acid, 97%

Codice CAS
87199-17-5
Sinonimi
4-Boronobenzaldehyde
4-Formylphenylboronic acid

Dimensioni Prezzo ($) Quantità Disponibilità
1g 29,60
5g 87,80
25g 322,00
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4-Formylbenzeneboronic acid, 97%

MDL
MFCD00151823
EINECS
438-670-5

Proprietà chimiche

Formula
C7H7BO3
Peso formula
149.94
Punto di fusione
260-266°
Sensibilità
Air Sensitive
Solubilità
Slightly Soluble in water.

Applicazioni

4-Formylbenzeneboronic acid acts as a reagent used for Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids, triethylamine-catalyzed three-component Hantzsch condensations, copper-catalyzed nitrations, oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta, palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides, palladium-catalyzed aerobic oxidative cross-coupling reactions. It acts as a reagent used in preparation of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells, a novel protein synthesis inhibitor active against Gram-positive bacteria.

Note

Air Sensitive. Store away from air and oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Letteratura

Qingqing Qi; Qilong Shen; Long Lu. Copper-mediated aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides at room temperature. Journal of the American Chemical Society.2012, 134, (15), 6548-6551.

Sartori Guillaume; Enderlin Gerald; Herve Gwénaelle; Len Christophe. Highly Effective Synthesis of C-5-Substituted 2'-Deoxyuridine Using Suzuki?Miyaura Cross-Coupling in Water. Synthesis.2012, 44, 767-772.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H317

May cause an allergic skin reaction.

Dichiarazioni precauzionali: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
3030770
Codice tariffe armonizzato
2931.90
TSCA
Yes

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