Informativa e consenso per l'uso dei cookie

Accetto Il nostro sito salva piccoli pezzi di informazioni (cookie) sul dispositivo, al fine di fornire contenuti migliori e per scopi statistici. È possibile disattivare l'utilizzo di cookies modificando le impostazioni del tuo browser. Continuando la navigazione si acconsente all'utilizzo dei cookie.

74289-57-9 - Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90% - Bis(3,5-dimethylphenyl)chlorophosphine - Chlorodi(3,5-xylyl)phosphine - H25885 - Alfa Aesar

H25885 Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%

Codice CAS
74289-57-9
Sinonimi
Bis(3,5-dimethylphenyl)chlorophosphine
Chlorodi(3,5-xylyl)phosphine

Dimensioni Prezzo ($) Quantità Disponibilità
1g 82,71
5g 315,18
Aggiungi al carrello Aggiungi al preventivo generale Visualizza articolo

Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%

MDL
MFCD01630841
EINECS
000-000-0

Proprietà chimiche

Formula
C16H18ClP
Peso formula
276.75
Sensibilità
Air & Moisture Sensitive
Solubilità
Reacts with water.

Applicazioni

Chlorobis(3,5-dimethylphenyl)phosphine is used in the synthesis of (S)- and (R)-2,2?-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5?,6,6?,7,7?,8,8?-octahydro-1,1?-binaphthyl (Xyl-H 8 -BINAPO).

Note

Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, bases.

Letteratura

Rongwei Guo,; Terry T.-L. Au-Yeung,; Jing Wu,; Michael C.K. Choi,;, Albert S.C. Chan. Modified BINAPO ligands for Rh-catalysed enantioselective hydrogenation of acetamidoacrylic acids and esters. Tetrahedron: Asymmetry. 2002, 13 (23), 2519-2522.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • H25883

    Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25888

    Chlorobis[4-(trifluoromethyl)phenyl]phosphine, 97%
  • H25889

    Chlorodi(p-tolyl)phosphine, 95%
  • H26953

    Chlorobis(4-fluorophenyl)phosphine, 98%

Visualizzati di recente

Prodotti chimici

Scienze della vita

Metalli e materiali

Catalizzatori

Apparecchiature di analisi e di laboratorio