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1019-71-2 - Chlorodi(p-tolyl)phosphine, 95% - Di(p-tolyl)chlorophosphine - Chlorobis(4-methylphenyl)phosphine - H25889 - Alfa Aesar

H25889 Chlorodi(p-tolyl)phosphine, 95%

Codice CAS
1019-71-2
Sinonimi
Di(p-tolyl)chlorophosphine
Chlorobis(4-methylphenyl)phosphine

Dimensioni Prezzo ($) Quantità Disponibilità
1g 87,55
5g 305,91
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Chlorodi(p-tolyl)phosphine, 95%

MDL
MFCD01630844
EINECS
000-000-0

Proprietà chimiche

Formula
C14H14ClP
Peso formula
248.69
Punto di ebollizione
180-184°/10mm
Densità
1.159
Sensibilità
Air & Moisture Sensitive
Solubilità
Reacts with water.

Applicazioni

Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

Note

Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.

Letteratura

Chi-Feng Lin; Iwao Ojima. Formal enantioselective total synthesis of schulzeines A-C via Pd-catalyzed intramolecular asymmetric allylic amination. Journal of Organic Chemistry. 2011, 76 (15), 6240-6249.

X. Ren; L. Wang and Y. Li. 1,1'-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]ferrocene. Acta Cryst. 2012, 68, 922.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • H25883

    Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals
  • H25885

    Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25888

    Chlorobis[4-(trifluoromethyl)phenyl]phosphine, 97%
  • H25890

    Chlorodi(o-tolyl)phosphine, 98%

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