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263369-88-6 - Chlorobis(2-methoxyphenyl)phosphine, 98+% - Bis(2-methoxyphenyl)chlorophosphine - H25894 - Alfa Aesar

H25894 Chlorobis(2-methoxyphenyl)phosphine, 98+%

Codice CAS
263369-88-6
Sinonimi
Bis(2-methoxyphenyl)chlorophosphine

Dimensioni Prezzo ($) Quantità Disponibilità
1g 101,00
5g 307,00
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Chlorobis(2-methoxyphenyl)phosphine, 98+%

MDL
MFCD08064037
EINECS
000-000-0

Proprietà chimiche

Formula
C14H14ClO2P
Peso formula
280.69
Punto di fusione
111-114°
Sensibilità
Air & Moisture Sensitive
Solubilità
Reacts with water.

Applicazioni

Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

Note

Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.

Letteratura

Anna Trifonova; Jarle S. Diesen; Pher G. Andersson Prof. Dr. Asymmetric Hydrogenation of Imines and Olefins Using Phosphine-Oxazoline Iridium Complexes as Catalysts. Chemistry - A European Journal. 2006, 12 (8), 2318-2328.

Sandra Brun; Magda Parera; Anna Pla-Quintana; Anna Roglans; Thierry León; Thierry Achard; Jordi Solà; Xavier Verdaguer; Antoni Riera. Chiral N-phosphino sulfinamide ligands in rhodium(I)-catalyzed [2+2+2] cycloaddition reactions. Tetrahedron. 2010, 66 (46), 9032-9040.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • H25882

    Bis(3,5-di-tert-butyl-4-methoxyphenyl)chlorophosphine, 94%
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25889

    Chlorodi(p-tolyl)phosphine, 95%
  • H25890

    Chlorodi(o-tolyl)phosphine, 98%

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