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59831-02-6 - Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II) - [1,3-Bis(diphenylphosphino)propane]dichloropalladium(II) - H26897 - Alfa Aesar

H26897 Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II)

Codice CAS
59831-02-6
Sinonimi
[1,3-Bis(diphenylphosphino)propane]dichloropalladium(II)

Dimensioni Prezzo ($) Quantità Disponibilità
250mg 90,00
1g 225,00
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Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II)

MDL
MFCD03844773

Proprietà chimiche

Formula
C27H26Cl2P2Pd
Peso formula
589.77
Sensibilità
Air Sensitive
Solubilità
Soluble in dichloromethane.

Applicazioni

(1,3-Bis(diphenylphosphino)propane)palladium(II) chloride, used ubiquitously as a employed preparation of palladium for cross-coupling protocols in organic synthesis. It is also a useful organo-metallic chemical catalyst. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is also used in coupling reactions.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents. Air Sensitive.

Letteratura

CS Shultz.; J Ledford.; JM DeSimone. Kinetic Studies of Migratory Insertion Reactions at the (1,3-Bis(diphenylphosphino)propane)Pd(II) Center and Their Relationship to the Alternating Copolymerization of Ethylene and Carbon Monoxide. J. Am. Chem. Soc. 2000122 (27), 6351-6356.

M Sundermeier.; A Zapf.; M Beller.; J Sans. A new palladium catalyst system for the cyanation of aryl chlorides. Tetrahedron Letters. 200142 (38), 6707-6710.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2843.90
TSCA
No

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