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2526-64-9 - Triphenylphosphine dichloride, 96% - Dichlorotriphenylphosphorane - H27436 - Alfa Aesar

H27436 Triphenylphosphine dichloride, 96%

Codice CAS
2526-64-9
Sinonimi
Dichlorotriphenylphosphorane

Dimensioni Prezzo ($) Quantità Disponibilità
25g 43,10
100g 144,00
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Triphenylphosphine dichloride, 96%

MDL
MFCD00010359

Proprietà chimiche

Formula
(C6H5)3PCl2
Peso formula
333.19
Punto di fusione
84-86°
Sensibilità
Moisture Sensitive
Solubilità
Reacts with water.

Applicazioni

As a precursor to fire-retardant materials. Mainly used as a chlorinating agent widely used in organic chemistry. Applications include the conversion of alcohols and ethers to alkyl chlorides, the cleavage of epoxides to vicinal dichlorides and the chlorination of carboxylic acids to acyl chlorides.

Note

Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, bases, air, moisture.

Letteratura

Shinichiro Kitayama,; Kohei Sanui,; Naoya Ogata. Synthesis of aromatic polyesters by direct polycondensation with triphenylphosphine dichloride. Journal of Polymer Science. 1984, 22 (10), 2705-2712.

Tomotake Yano,; Manabu Kuroboshi,; Hideo Tanaka. Electroreduction of triphenylphosphine dichloride and the efficient one-pot reductive conversion of phosphine oxide to triphenylphosphine. Tetrahedron Letters. 2010 , 51(4),698-701.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

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