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99769-19-4 - 3-(Methoxycarbonyl)benzeneboronic acid, 97% - 3-(Methoxycarbonyl)phenylboronic acid - Methyl 3-boronobenzoate - H27444 - Alfa Aesar

H27444 3-(Methoxycarbonyl)benzeneboronic acid, 97%

Codice CAS
99769-19-4
Sinonimi
3-(Methoxycarbonyl)phenylboronic acid
Methyl 3-boronobenzoate

Dimensioni Prezzo ($) Quantità Disponibilità
1g 59,70
5g 174,00
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3-(Methoxycarbonyl)benzeneboronic acid, 97%

MDL
MFCD02093046

Proprietà chimiche

Formula
C8H9BO4
Peso formula
179.97
Punto di fusione
136°
Solubilità
Reacts with water.

Applicazioni

Reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration, cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. Reagent used in Preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6, chromenones and their bradykinin B1 antagonistic active, Pt nanoparticles at Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injecti, salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

Kiyofumi Inamoto et. al.Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones.. Chemical Communications. 2012, 48(36),4332-4334.

Qingqing Qi et. al. Copper-mediated aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides at room temperature. Journal of the American Chemical Society. 2012 , 134 (15), 6548-6551.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2931.90
TSCA
No

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