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1504-06-9 - 3-Methyloxindole, 96% - H27662 - Alfa Aesar

H27662 3-Methyloxindole, 96%

Codice CAS
1504-06-9
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 39,20
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3-Methyloxindole, 96%

MDL
MFCD04037370

Proprietà chimiche

Formula
C9H9NO
Peso formula
147.18
Punto di fusione
121-124°
Solubilità
Insoluble in water.

Applicazioni

A versatile reactant. As 3-Methylindole metabolite. Reactant for enantioselective α-amination reactions, Reactant for aldol reaction with glyoxal derivatives, Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes, Reactant for O-acetylation reactions, Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

Zhigang Yang et. al. Highly enantioselective synthesis of 3-amino-2-oxindole derivatives: catalytic asymmetric alpha-amination of 3-substituted 2-oxindoles with a chiral scandium complex. . Chemistry: A European Journal. 2010, 16(22),6632-6637.

Lanza, D., et al Drug Metab. Disposition. 2001, 29 (950)

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni precauzionali: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2933.79
TSCA
No

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