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139143-09-2 - 1,3-Diisopropylimidazolium chloride, 97+% - H27798 - Alfa Aesar

H27798 1,3-Diisopropylimidazolium chloride, 97+%

Codice CAS
139143-09-2
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 45,11
5g 136,97
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1,3-Diisopropylimidazolium chloride, 97+%

MDL
MFCD03840577

Proprietà chimiche

Formula
C9H17ClN2
Peso formula
188.69
Punto di fusione
182-186°
Sensibilità
Moisture Sensitive
Solubilità
Soluble in water.

Applicazioni

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Note

Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture.

Letteratura

Ian R. Baxendale Dr.,; Steven V. Ley Prof.,; Andrew C. Mansfield2,; Christopher D. Smith Dr. Multistep Synthesis Using Modular Flow Reactors: Bestmann-Ohira Reagent for the Formation of Alkynes and Triazoles. Angewandte Chemie . 2009, 48(22),4017-4021,.

.Structural characterization of Group 4 transition metal halide bis-Arduengo carbene complexes MCl4L2:: X-ray crystal structure analyses and DFT calculations. Journal of Organometallic Chemistry. 2002, 663 (1-2), 192-203.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2933.29
TSCA
No

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