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4385-76-6 - 4-(4-Pyridyl)benzoic acid, 97% - H27882 - Alfa Aesar

H27882 4-(4-Pyridyl)benzoic acid, 97%

Codice CAS
4385-76-6
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
250mg 52,94
1g 125,66
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4-(4-Pyridyl)benzoic acid, 97%

MDL
MFCD04114574

Proprietà chimiche

Formula
C12H9NO2
Peso formula
199.20
Punto di fusione
>300°
Solubilità
Slightly soluble in water.

Applicazioni

Self-assembly of 4-(4-pyridyl)benzoic acid (pybenH), Ni2+, SCN- and an aromatic guest (naphthalene or dibenz[a,h]anthracene) gave two isostructural inclusion compounds, in which pybenH ligands form the corresponding dimers acting as bidentate building blocks with a length of ca. 20.86 Å. By replacing an isonicotinic acid dimer with a 4-(4-pyridyl)benzoic acid (pybenH) dimer, new inclusion compounds in which pybenH dimers function as bridging ligands of ca. 21 Å.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

Ryo Sekiya1),; Shin-ichi Nishikiori1),; Katsuyuki Ogura2). 4-(4-Pyridyl)benzoic Acid (PybenH) Dimer: An Efficient and Reasonable Design for a Long Linear Bidentate Building Block Employed in Metal-Organic Coordination Framework . Chemistry Letters. 2006, 35(6), 614-615.

Ryo Sekiya,; Shin-ichi Nishikiori. Structural Extension from an Isonicotinic Acid Dimer to 4-(4-Pyridyl)benzoic Acid (pybenH) Dimer: X-ray Crystal Structure Analysis and Inclusion Properties of a Hydrogen-Bonded Coordination Polymer [Ni(SCN)2(pybenH)2]. Cryst. Growth Des. 2011, 11(12), 5574-5591.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2933.39
TSCA
No

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