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100846-24-0 - 5-(Trifluoromethyl)indole, 98% - H28782 - Alfa Aesar

H28782 5-(Trifluoromethyl)indole, 98%

Codice CAS
100846-24-0
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
100mg 112,00
500mg 343,00
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5-(Trifluoromethyl)indole, 98%

MDL
MFCD03095341

Proprietà chimiche

Formula
C9H6F3N
Peso formula
185.15
Punto di fusione
68-71°

Applicazioni

In 3-Naphthylindole construction by rhodium (II)-catalyzed regioselective direct arylation of indoles with 1-diazonaphthalen-2-(1H)-ones treatment of 5-(trifluoromethyl)indole(1k) or 6-(trifluoromethyl)indole (1l) with 2a afforded the desired products 3k (86%)and 3l (86%).

Note

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light.

Letteratura

Ek Raj Baral,; Yong Rok Lee1,; Sung Hong Kim2. 3-Naphthylindole Construction by Rhodium(II)-Catalyzed Regioselective Direct Arylation of Indoles with 1-Diazonaphthalen-2-(1H)-ones. Advanced Synthesis & Catalysis. 2015, 357 (13),2883-2892.

Larisa V. Politanskaya,; Igor P. Chuikov,; Vitalij D. Shteingarts. Synthesis of indoles with a polyfluorinated benzene ring . Tetrahedron. 2013 , 69 (39),8477-8486.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2933.99
TSCA
No

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