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29415-97-2 - Methyl 3-bromo-4-hydroxybenzoate, 98% - 3-Bromo-4-hydroxybenzoic acid methyl ester - H30222 - Alfa Aesar

H30222 Methyl 3-bromo-4-hydroxybenzoate, 98%

Codice CAS
29415-97-2
Sinonimi
3-Bromo-4-hydroxybenzoic acid methyl ester

Dimensioni Prezzo ($) Quantità Disponibilità
10g 44,60
50g 178,19
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Methyl 3-bromo-4-hydroxybenzoate, 98%

MDL
MFCD06203850

Proprietà chimiche

Formula
C8H7BrO3
Peso formula
231.05
Punto di fusione
108-110°

Applicazioni

A reactant used in the preparation of selective inhibitors. In unsymmetrical Ullman reaction between methyl 5bromovanillate (II) and methyl 3-bromo-4-hydroxybenzoate (III) yielded all the three possible dicarbomethoxy-dibenzo-pdioxms which were separated by repeated chromatography over silica gel. A phosphorus- and bromine-containing bifunctional monomer has been prepared from bis(chloromethyl)methylphosphine oxide and the sodium salt of methyl 3-bromo-4-hydroxybenzoate.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

H. Sivriev ,; G. Borissov ,; T.E. Kron,; E.N. Tsvetkov,; M.I. Kabachnik. Polyesters based on bromine-containing bis(p-methoxycarbonylphenoxymethyl)-methylphosphine oxide. European Polymer Journal. 15 (8),771-774.

B. Anjaneyulu,; T.R. Govindachari,; N. Viswanathan.Total synthesis of dl-O-methyltiliacorine . Tetrahedron. 1971, 27 (2) , 439-443.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2918.29
TSCA
No

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