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It has also been found that 2,3-dimethylthiophene can be formylated to yield a dimethylthiophene aldehyde, which as expected proved to have the aldehyde group in the free a-position.
S Gronowitz,; V Pavulans. The Signs of the Methyl-Methyl Spin Couplings in 2, 3-Dimethylthiophene, 2, 3-Dimethylfuran. Acta Chemica. 1966, 20 2515-2526.
William J. King,; F. F. Nord. Studies In the Thiophene Series. V. Wolf-Kishner Reductions. J. Org. Chem. 1949, 14 (4), 638-642.
Dichiarazioni di rischio (UE): H226-H332
Flammable liquid and vapour. Harmful if inhaled.
Dichiarazioni precauzionali: P210-P261-P280a-P303+P361+P353-P304+P340-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Dispose of contents/container in accordance with local/regional/national/international regulations.