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33527-91-2 - Tris(2-dimethylaminoethyl)amine, 99+% - Me6TREN - H31853 - Alfa Aesar

H31853 Tris(2-dimethylaminoethyl)amine, 99+%

Codice CAS
33527-91-2
Sinonimi
Me6TREN

Dimensioni Prezzo ($) Quantità Disponibilità
5g 118,00
25g 394,00
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Tris(2-dimethylaminoethyl)amine, 99+%

MDL
MFCD00015607

Proprietà chimiche

Formula
C12H30N4
Peso formula
230.40
Punto di ebollizione
70-71°/0.5mm
Indice di rifrazione
1.4540
Sensibilità
Air Sensitive & Hygroscopic
Solubilità
Miscible with water.

Applicazioni

Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

Note

Hygroscopic. Air sensitive. Incompatible with oxidizing agents, acids.

Letteratura

Samanta, S. R.; Cai, R.; Percec, V. A rational approach to activated polyacrylates and polymethacrylates by using a combination of model reactions and SET-LRP of hexafluoroisopropyl acrylate and methacrylate. Polym. Chem. 2015, 6 (17), 3259-3270.

Citek, C.; Herres-Pawlis, S.; Stack, T. D. P. Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models. Acc. Chem. Res. 2015, 48 (8), 2424-2433.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
8
Gruppo di imballaggio
III
Codice tariffe armonizzato
2921.29
TSCA
Yes

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