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10294-34-5 - Boron trichloride, 1M soln. in hexanes, mixed isomers - H32833 - Alfa Aesar

H32833 Boron trichloride, 1M soln. in hexanes, mixed isomers

Codice CAS
10294-34-5
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 63,36
500ml 211,50
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Boron trichloride, 1M soln. in hexanes, mixed isomers

MDL
MFCD00011313
EINECS
233-658-4

Proprietà chimiche

Formula
BCl3
Peso formula
117.17
Densità
0.738
Sensibilità
Moisture Sensitive
Solubilità
Reacts with water.

Applicazioni

A mild, selective combination reagent for the cleavage of primary alkyl aryl ethers. Boron trichloride is a selective demethylating agent. For preparing methyl esters of fatty acids and for transesterification of triglycerides. Mainly used as semiconductor silicon doping source or organic synthesis catalyst, also used for making high purity boron or organic boron.

Note

Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, heat. Unstable. Store at 2-8°C.

Letteratura

F.M. Dean,; J.Goodchild,; L.E. Houghton,; J.A. Martin,; R.B. Morton,; B. Parton,; A.W. Price, ;Nongyow Somvichien. Boron trichloride as a selective demethylating agent. Tetrahedron Letters. 1996, 7(35),4153-4159.

N. N. Greenwood,; K. Wade .Complexes of boron trichloride with pyridine and piperidine. J. Chem. Soc., year of publication , 1130-1141.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H300-H331-H336-H304-H361-H373-H314-H411

Highly flammable liquid and vapour. Fatal if swallowed. Toxic if inhaled. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. Toxic to aquatic life with long lasting effects.

Dichiarazioni precauzionali: P210-P260-P201-P261-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2812.10
TSCA
Yes

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