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A mild, selective combination reagent for the cleavage of primary alkyl aryl ethers. Boron trichloride is a selective demethylating agent. For preparing methyl esters of fatty acids and for transesterification of triglycerides. Mainly used as semiconductor silicon doping source or organic synthesis catalyst, also used for making high purity boron or organic boron.
F.M. Dean,; J.Goodchild,; L.E. Houghton,; J.A. Martin,; R.B. Morton,; B. Parton,; A.W. Price, ;Nongyow Somvichien. Boron trichloride as a selective demethylating agent. Tetrahedron Letters. 1996, 7(35),4153-4159.
N. N. Greenwood,; K. Wade .Complexes of boron trichloride with pyridine and piperidine. J. Chem. Soc., year of publication , 1130-1141.
Dichiarazioni di rischio (UE): H225-H300-H331-H314-H318-H361-H336-H373-H304
Highly flammable liquid and vapour. Fatal if swallowed. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of damaging fertility or the unborn child. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways.
Dichiarazioni precauzionali: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.