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5-Amino-2-bromo-3-fluoropyridine, 97% - H33154 - Alfa Aesar

H33154 5-Amino-2-bromo-3-fluoropyridine, 97%

Codice CAS
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
250mg 62,40
1g 173,00
5g 580,00
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5-Amino-2-bromo-3-fluoropyridine, 97%

MDL
MFCD21099397

Proprietà chimiche

Formula
C5H4BrFN2
Peso formula
191.00
Punto di fusione
114-118°

Applicazioni

Commercially available 5-bromo-2-fluoropyridine was treated with LDA at -78°C to give the lithiated species. Fluoropyridine-based bromoacetamide reagent has been prepared and used in prosthetic group introduction for the labeling of oligonucleotides.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Refrigerate(2-7°C ).

Letteratura

Bryan W. Stroup,; Paul V. Szklennik,; Cornelia J. Forster,; Michael H. Serrano-Wu.Chemoselective Amination of 5-Bromo-2-chloro-3-fluoropyridine. Org. Lett.,. 2007, 9(10),2039-2042.

Bertrand Kuhnast,; Béatrice de Bruin,; Françoise Hinnen,; Bertrand Tavitia,; Frédéric Dollé .Design and Synthesis of a New [18F]Fluoropyridine-Based Haloacetamide Reagent for the Labeling of Oligonucleotides:? 2-Bromo-N-[3-(2-[18F]fluoropyridin-3-yloxy)propyl]acetamide . Bioconjugate Chem.,. 2004, 15 (3), 617-627.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2933.39
TSCA
No

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