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89719-92-6 - 2,5-Dichloro-4-(trifluoromethyl)pyridine, 97% - H33442 - Alfa Aesar

H33442 2,5-Dichloro-4-(trifluoromethyl)pyridine, 97%

Codice CAS
89719-92-6
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
250mg 70,90
1g 197,00
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2,5-Dichloro-4-(trifluoromethyl)pyridine, 97%

MDL
MFCD09749663

Proprietà chimiche

Formula
C6H2Cl2F3N
Peso formula
215.99
Punto di ebollizione
76°/18mm

Applicazioni

2-chloro-6-(trifluoromethyl)pyridine, 2-chloro-5-(trifluoromethyl)pyridine and 3-chloro-4-(trifluoromethyl)pyridine were each converted into the three possible carboxylic acids 2, 4, 6,8, 10, 12, 16, 17 and 20. This was achieved by employing several, but not all of the organometallic “toolbox methods”: transformation of a more basic organometallic species into a less basic isomer by transmetalation-equilibration.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, aluminum. Protection under nitrogen and lower temperature is recommended(below 4 deg C).

Letteratura

Florence Mongin,; Antonio Tognini,; Fabrice Cottet,; Manfred Schlosses. Halogen shuffling in pyridines: Site selective electrophilic substitutions of 2-chloro-6-(trifluoromethyl)pyridine. Tetrahedron Letters. 1998, 39(13), 1749-1752.

Fabrice Cottet,; Marc Marull,; Olivier Lefebvre,; Manfred Schlosser. Recommendable Routes to Trifluoromethyl-Substituted Pyridine- and Quinolinecarboxylic Acids. European Journal of Organic Chemistry. 2003, 81559-1568,.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H226-H301-H315-H319-H335

Flammable liquid and vapour. Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P260-P201-P280a-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves and eye/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
3
Gruppo di imballaggio
III
Codice tariffe armonizzato
2933.39
TSCA
No

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