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37598-27-9 - Iridium acetate, Ir 48-54% - H34028 - Alfa Aesar

H34028 Iridium acetate, Ir 48-54%

Codice CAS
37598-27-9
Sinonimi

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Iridium acetate, Ir 48-54%

MDL
MFCD22988919

Proprietà chimiche

Formula
Ir(CH3COO)n
Punto di fusione
>100°
Solubilità
Insoluble in water.

Applicazioni

Mostly used in wax oil catalytic cracking and heavy oil catalytic cracking. The catalytic water-oxidation activity of Wilkinson's iridium acetate trimer has been characterized electrochemically and by using chemical oxidants. Results show it can function as an operationally homogeneous water-oxidation catalyst when driven with sodium periodate as a primary oxidant, but rapidly decomposes using Ce(IV) as a primary oxidant.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

Tomotaka Hirabayashi,; Satoshi Sakaguchi,; Yasutaka Ishii. Iridium-Catalyzed Synthesis of Vinyl Ethers from Alcohols and Vinyl Acetate. Organic Syntheses. year of publication , volume issue , pg no.

Alexander R. Parent,; James D. Blakemore,; Gary W. Brudvig,; Robert H. Crabtree. Wilkinson's iridium acetate trimer as a water-oxidation catalyst. Chem. Commun., . 2011, 47 (42),11745-11747.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H318-H317-H413

Causes serious eye damage. May cause an allergic skin reaction. May cause long lasting harmful effects to aquatic life.

Dichiarazioni precauzionali: P261-P273-P280-P305+P351+P338-P310-P363-P321-P333+P313-P302+P352-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Specific treatment (see label). If skin irritation or rash occurs: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2843.90
TSCA
No

Raccomandato

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    Dodecacarbonyltriruthenium, 99%
  • 11031

    Dihydrogen hexachloroiridate(IV) hydrate, 99% (metals basis), Ir 38-42%
  • 11044

    Platinum(II) chloride, 99.9% (metals basis), Pt 73% min
  • 12158

    Iridium(III) chloride, anhydrous, Ir 62% min
  • 12169

    Potassium hexachloroplatinate(IV), Pt 39.6%

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