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14077-58-8 - 2-Ethoxyacetyl chloride, 97%, stab. with 0.3% Magnesium oxide - H34443 - Alfa Aesar

H34443 2-Ethoxyacetyl chloride, 97%, stab. with 0.3% Magnesium oxide

Codice CAS
14077-58-8
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 50,00
25g 185,00
100g 536,00
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2-Ethoxyacetyl chloride, 97%, stab. with 0.3% Magnesium oxide

MDL
MFCD11170566
EINECS
237-930-3

Proprietà chimiche

Formula
C4H7ClO2
Peso formula
122.55
Solubilità
Insoluble in water.

Applicazioni

It is employed in fine chemical syntheses and used as pharmaceutical intermediates. A trace of cis-ethoxyacetamide was also detected and isolated with an authentic sample prepared from the reaction of cis-3-amino-6-methylchroman-4-01 (2) with 2-ethoxyacetyl chloride.

Note

Reacts with strong oxidizing agents. Store at room temperature.

Letteratura

Karen K. Bach.; Hesham R. El-Seedi.; Henrik M. Jensen.; Helene B. Nielsen.; Ib Thomsen.; Kurt B.G. Torssell. 1,3-Dipolar cycloadditions of ethoxycarbonyl-nitrile benzylimine, EtOOC C ? Full-size image (<1 K) - Full-size image (<1 K) CH2C6H5, and synthesis of β-amino acids. Synthesis and reactions of ethyl 2-chloro-2-ethoxyacetate and 2-chloro-2-ethoxyacetyl chloride. Tetrahedron. 1994, 50 (25),7543-7556.

Gordon W. Rewcastle.; Hamish S. Sutherland.; Claudette A. Weir.; Adrian G. Blackburn.; William A. Denny. An improved synthesis of isonitrosoacetanilides. Tetrahedron Lett. 2005, 46 (50),8719-8721.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H226-H332-H314-H318

Flammable liquid and vapour. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2918.99
TSCA
No

Raccomandato

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    Sulfur trioxide-pyridine complex, 98%, active SO3 ca 48-50%
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    Ethoxyacetic acid, 98%
  • L03210

    Methoxyacetyl chloride, 97%, stab. with ca 0.3% magnesium oxide
  • H55211

    2-(Boc-amino)ethyl bromide, 96%

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