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23719-80-4 - Cyclopropylmagnesium bromide, 0.5M in MeTHF - H51158 - Alfa Aesar

H51158 Cyclopropylmagnesium bromide, 0.5M in MeTHF

Codice CAS
23719-80-4
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 142,00
100ml 224,00
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Cyclopropylmagnesium bromide, 0.5M in MeTHF

MDL
MFCD00672094

Proprietà chimiche

Formula
C3H5BrMg
Peso formula
145.28
Sensibilità
Air & Moisture Sensitive
Solubilità
Reacts with water.

Applicazioni

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Note

Air and Moisture Sensitive, store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Letteratura

H. M. Walborsky; Christoph Zimmermann. The surface nature of Grignard reagent formation.J. Am. Chem. Soc.,1992, 114(13), 4996-5000.

Chutian Shu; Kanwar Sidhu; Li Zhang; Xiao-jun Wang; Dhileepkumar Krishnamurthy; and Chris H. Senanayake. Palladium-Catalyzed Cross-Coupling of Cyclopropylmagnesium Bromide with Aryl Bromides Mediated by Zinc Halide Additives. J. Org. Chem., 2010, 75(19), 6677-6680.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H313-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. May be harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

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