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913835-92-4 - 2-Chloro-5-(methoxycarbonyl)benzeneboronic acid, 98% - Methyl 3-borono-4-chlorobenzoate - 2-Chloro-5-(methoxycarbonyl)phenylboronic acid - H52999 - Alfa Aesar

H52999 2-Chloro-5-(methoxycarbonyl)benzeneboronic acid, 98%

Codice CAS
913835-92-4
Sinonimi
Methyl 3-borono-4-chlorobenzoate
2-Chloro-5-(methoxycarbonyl)phenylboronic acid

Dimensioni Prezzo ($) Quantità Disponibilità
250mg 56,10
1g 180,00
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2-Chloro-5-(methoxycarbonyl)benzeneboronic acid, 98%

MDL
MFCD08689528

Proprietà chimiche

Formula
C8H8BClO4
Peso formula
214.41
Punto di fusione
230-232°

Applicazioni

Boronic acids are often used in metal-catalyzed cross-coupling for C-C, C-N bond formation, and C-H functionalization. The widely utilized Suzuki-Miyaura coupling allows for the coupling of boronic acids with carbon halides and surrogates. Other known chemistry may includes 1,4-addition to activated alkenes, 1,2-addition to carbonyls and imines, addition to anhydrides, 1,4-addition to a,ß-unsaturated ketones(4), and 1,4-addition to esters and amides.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

Green, I. R.; et al. 2-Arylnaphthoquinone analogues: potential anti-TB and pro-apoptotic agents. Journal name. 2011, 192-212.

Tomohiro Yasukawa et. al.Copper-catalyzed, aerobic oxidative cross-coupling of alkynes with arylboronic acids: remarkable selectivity in 2,6-lutidine media.. Organic & Biomolecular Chemistry. 2011, 9(18), 6208-6210.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2931.90
TSCA
No

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