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1671-87-0 - 3,6-Di-2-pyridyl-1,2,4,5-tetrazine, 96% - H53484 - Alfa Aesar

H53484 3,6-Di-2-pyridyl-1,2,4,5-tetrazine, 96%

Codice CAS
1671-87-0
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 34,20
5g 128,00
25g 511,00
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3,6-Di-2-pyridyl-1,2,4,5-tetrazine, 96%

MDL
MFCD00121717

Proprietà chimiche

Formula
C12H8N6
Peso formula
236.24
Punto di fusione
225° dec.
Solubilità
Slightly soluble in water.

Applicazioni

3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis. It also may be used in the synthesis of novel cyclic tetranuclear ZnII complex and synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.

Note

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Letteratura

Xian-He Bu; Hiromasa Morishita; Kentaro Tanaka; Kumar Biradha; Sanae Furusho; Mitsuhiko Shionoya. A spontaneously resolved chiral molecular box: a cyclic tetranuclear ZnIIcomplex with DPTZ (DPTZ = 3,6-di-2-pyridyl-1,2,4,5-tetrazine) . Chem. Commun. 2000, (11),971-972

 

Jiehu Cui; Liangfang Huang; Zhenzhong Lu; Yizhi Li; Zijian Guo; Hegen Zheng. Synthesis and properties of five unexpected copper complexes with ring-cleavage of 3,6-di-2-pyridyl-1,2,4,5-tetrazine by one pot in situ hydrothermal reaction. CrystEngComm. 2012, 14, (6),2258-2267

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2933.99
TSCA
No

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