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34696-73-6 - 3,5-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF - H54057 - Alfa Aesar

H54057 3,5-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF

Codice CAS
34696-73-6
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 167,00
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3,5-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF

MDL
MFCD01311497

Proprietà chimiche

Formula
C8H9BrMg
Peso formula
209.37
Sensibilità
Air & Moisture Sensitive
Solubilità
It reacts with water.

Applicazioni

3,5-Dimethylphenylmagnesium bromide is used as pharmaceutical intermediate.

Note

Air and moisture sensitive. Incompatible with oxidizing agents and bases.

Letteratura

Hidehiko Sasaki; Ryo Irie; Tetsuya Hamada; Kenji Suzuki; Tsutomu Katsuki. Rational design of Mn-salen catalyst (2): Highly enantioselective epoxidation of conjugated cis olefins. Tetrahedron. 1994, 50, (41),11827-11838

 

Derick D.Winkle; Kevin M.Schaab. Suzuki reaction of a diarylborinic acid:? One-pot preparation and cross-coupling of bis(3,5-dimethylphenyl)borinic acid. Org. Proc. Res. Dev. 2001, 5, (4),450-451

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H314-H313

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. May be harmful in contact with skin.

Dichiarazioni precauzionali: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • H54234

    5-Fluoro-2-methylphenylmagnesium bromide, 0.50 M in 2-MeTHF
  • H54622

    3,5-Difluorophenylmagnesium bromide, 0.50M in 2-MeTHF
  • H54337

    2,5-Dimethoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

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