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100-76-5 - Quinuclidine, 97+% - 1-Azabicyclo[2.2.2]octane - H54498 - Alfa Aesar

H54498 Quinuclidine, 97+%

Codice CAS
100-76-5
Sinonimi
1-Azabicyclo[2.2.2]octane

Dimensioni Prezzo ($) Quantità Disponibilità
250mg 42,75
1g 131,84
5g 329,60
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Quinuclidine, 97+%

MDL
MFCD00006690
EINECS
202-887-1

Proprietà chimiche

Formula
C7H13N
Peso formula
111.19
Punto di fusione
157-160°
Sensibilità
Air Sensitive
Solubilità
Soluble in alcohol, diethyl ether, water and organic solvents.

Applicazioni

Quinuclidine acts as a catalyst, a chemical building block and is used in organic synthesis. It is employed to prepare quinine and alkaloids. It finds application as a ligand, which is useful in the studies of OsO<sub>4</sub>-catalyzed dihydroxylation of olefins. It plays an important role in the formation of onium salts used testing of PAC-antagonist activity.

Note

Air sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents and chloroformates.

Letteratura

Chan, F. Y.; Sun, N.; Leung, Y. C.; Wong, K. Y. Antimicrobial activity of a quinuclidine-based FtsZ inhibitor and its synergistic potential with beta-lactam antibiotics. J. Antibiot. 2015, 68 (4), 253-258.

Reddi, Y.; Sunoj, R. B. Asymmetric Dual-Catalytic Cascade by Chiral N-Heterocyclic Carbene and Quinuclidine: Mechanism and Origin of Enantioselectivity in Benzofuranone Formation. ACS Catal. 2015, 5 (3), 1596-1603.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H301-H310-H315-H318

Toxic if swallowed. Fatal in contact with skin. Causes skin irritation. Causes serious eye damage.

Dichiarazioni precauzionali: P262-P280-P301+P310-P305+P351+P338-P361-P302+P350-P310-P362-P405-P501a

Do not get in eyes, on skin, or on clothing. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF ON SKIN: Gently wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,8081
Beilstein
103111
Classe di rischio
6.1
Gruppo di imballaggio
II
Codice tariffe armonizzato
2933.39
TSCA
Yes
RTECS
CL5594625

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