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1643-73-8 - 4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF - H54990 - Alfa Aesar

H54990 4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF

Codice CAS
1643-73-8
Sinonimi

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Aggiungi al preventivo generale

4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF

MDL
MFCD01319898

Proprietà chimiche

Formula
C7H6ClFMg
Peso formula
168.88
Sensibilità
Air & Moisture Sensitive
Solubilità
Reacts with water.

Applicazioni

4-Fluorobenzylmagnesium chloride is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Note

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to air and moisture. Protect from humidity and water. Store under dry inert gas.

Letteratura

Brian T. Gregg.; Kathryn C. Golden.; John F. Quinn.; Hong-Jun Wang.; Wei Zhang.; Ruifang Wang.; Francis Wekesa.; Dmytro O. Tymoshenko. Rapid, one-pot synthesis of α,α-disubstituted primary amines by the addition of Grignard reagents to nitriles under microwave heating conditions. Chemical Communications. 2009, 50 (27), 3978-3981.

Gang Wu.; Zhen-Wei Cai.; Mark S. Bednarz.; Octavian R. Kocy.; Ashvinikumar V. Gavai.; Jollie D. Godfrey.; William N. Washburn .; Michael A. Poss.; Philip M. Sher. Addition of Benzylic and Allylic Organozinc and Grignard Reagents to Resin-Bound Imines To Provide α-Branched Secondary Amines Bearing a Wide Variety of Functional Groups. Utility in the Synthesis of β-3 Adrenergic Receptor Agonists. J. Comb. Chem. 2005, 7 (1), 99-108.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H313-H314-H318

Highly flammable liquid and vapour. May be harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • H54966

    2,4-Difluorobenzylmagnesium bromide, 0.25M in 2-MeTHF

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