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56799-97-4 - 4-Methoxy-N-(1-naphthyl)benzenesulfonamide, 97% - H56822 - Alfa Aesar

H56822 4-Methoxy-N-(1-naphthyl)benzenesulfonamide, 97%

Codice CAS
56799-97-4
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
250mg 147,00
1g 470,00
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4-Methoxy-N-(1-naphthyl)benzenesulfonamide, 97%

MDL
MFCD00682767

Proprietà chimiche

Formula
C17H15NO3S
Peso formula
313.37

Applicazioni

N-(1-Naphthyl)benzenesulfonamides efficiently couple with internal alkynes via cleavage of the C-H bond at the peri-position in the presence of a catalyst system of [IrCl(cod)]2/PBut3 to selectively afford the corresponding 8-vinyl-1-naphthol derivatives.

Note

Store in a cool ventilated place. Avoid strong oxidizing materials.

Letteratura

Erik S. Vermeulen.; Marjan van Smeden.; Anne W. Schmidt.; Jeffrey S. Sprouse.; Håkan V. Wikström.; Cor J. Grol. Novel 5-HT7 Receptor Inverse Agonists. Synthesis and Molecular Modeling of Arylpiperazine- and 1,2,3,4-Tetrahydroisoquinoline-Based Arylsulfonamides.J. Med. Chem. 2004, 47 (22),5451-5466.

Chun-Jiang Wang.; Min Shi. Chiral Binaphthylthiophosphoramide-Cu(I)-Catalyzed Asymmetric Addition of Diethylzinc to N-Sulfonylimines.J. Org. Chem. 2003, 68 (16),6229-6237.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P312a-P321-P332+P313-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
3036729
Codice tariffe armonizzato
2935.90
TSCA
No

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