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131379-39-0 - 3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - 4-Ethoxy-4-oxobutylzinc bromide - H58023 - Alfa Aesar

H58023 3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
131379-39-0
Sinonimi
4-Ethoxy-4-oxobutylzinc bromide

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 135,00
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3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671977

Proprietà chimiche

Formula
C6H11BrO2Zn
Peso formula
260.44
Densità
0.976
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

Palladium-catalyzed coupling with [4-(methoxycarbonyl)benzyllzinc bromide then selective hydrolysis of the tert-butyl ester trifluoroacetic acid, in design and synthesis of pyridone-containing inhibitors.

Note

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents and heat.

Letteratura

Ilane Marek.; Jean-F. Normant. Synthesis and Reactivity of sp3-Geminated Organodimetallics. Chem. Rev. 1996, 96 (8),3241-3268.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Dichiarazioni precauzionali: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • H58248

    4-(Ethoxycarbonyl)butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

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