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Cyclobutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58247 - Alfa Aesar

H58247 Cyclobutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 456,00
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Cyclobutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD09801445

Proprietà chimiche

Formula
C4H7BrZn
Peso formula
200.38
Densità
0.984
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

This compound can be employed for cross coupling with acid chlorides, aryl halides, and substituted or non-substituted allyl halides. They may also undergo Michael Addition to unsaturated ketones or additions to alkynes to give substituted dienes.

Note

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Letteratura

Reuben D. Rieke.; Mark V. Hanson.; Jeffrey D. Brown.; Reuben D. Rieke.; Mark V. Hanson.; Jeffrey D. Brown. Direct Formation of Secondary and Tertiary Alkylzinc Bromides and Subsequent Cu(I)-Mediated Couplings. J. Org. Chem. 19960, 61 (8), 2726-2730.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H314-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.

Dichiarazioni precauzionali: P210-P231+P232-P260-P201-P261-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

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