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7565-59-5 - tert-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58351 - Alfa Aesar

H58351 tert-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
7565-59-5
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 164,00
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tert-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671989

Proprietà chimiche

Formula
C4H9BrZn
Peso formula
202.40
Densità
0.966
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

It is employed in cross couplig reactions.

Note

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Letteratura

M. V. Hanson.; R. D. Rieke. 1,4-Addition of secondary and tertiary alkylzinc bromides to .alpha.,.beta.-unsaturated ketones without a copper catalyst. J. Am. Chem. Soc. 1995, 117 (43),10775-10776.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Dichiarazioni precauzionali: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

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