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3-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58498 - Alfa Aesar

H58498 3-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 289,00
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3-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD11915899

Proprietà chimiche

Formula
C5H4BrNZn
Peso formula
223.38
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

3-Pyridylzinc bromide used in coupling reaction.

Note

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Letteratura

Seung-Hoi Kim; Reuben D. Rieke. 2-Pyridyl and 3-pyridylzinc bromides: direct preparation and coupling reaction. Tetrahedron. 2010, 66 (17), 3135-3146.

Nadja M. Simkovsky; Monika Ermann; Stanley M. Roberts; David M. Parry; and Andy D. Baxter. Some regioselective cross-coupling reactions of halopyridines and halopyrimidines. J. Chem. Soc., Perkin Trans. 1. 2002, (16), 1847-1849.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H303-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. May be harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Dichiarazioni precauzionali: P223-P210-P231+P232-P260u-P201-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Obtain special instructions before use. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2933.39
TSCA
No

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