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149923-10-4 - 4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58532 - Alfa Aesar

H58532 4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
149923-10-4
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 122,00
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4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD01319882

Proprietà chimiche

Formula
C7H6Cl2Zn
Peso formula
226.41
Densità
0.96
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

4-Chlorobenzylzinc chloride used as a intermediate for pharmaceutical.

Note

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Letteratura

Y. Fu; M. Yuan; X. Hu; Y. Yang; and H. Hou. 5-{2-(4-Chloro­phen­yl)-1-[2-(4-chloro­phen­yl)-1-(3,4,5-trimeth­oxy­phen­yl)eth­oxy]eth­yl}-1,2,3-trimeth­oxy­benzene. Acta Cryst.,2012, E68, o1007.

Zhi-Yong Peng; Fang-Fang Ma; Lv-Feng Zhu; Xiao-Min Xie; and Zhaoguo Zhang. Lewis Acid Promoted Carbon-Carbon Double-Bond Formation via Organozinc Reagents and Carbonyl Compounds. J. Org. Chem. 2009, 74 (17), 6855-6858.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H314

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage.

Dichiarazioni precauzionali: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

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