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77047-87-1 - Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - 2-Propylzinc bromide - H58536 - Alfa Aesar

H58536 Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
77047-87-1
Sinonimi
2-Propylzinc bromide

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 183,00
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Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD06200639

Proprietà chimiche

Formula
C3H7BrZn
Peso formula
188.37
Densità
0.963
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

Isopropylzinc bromide is employed in croos-coupling reactions.

Note

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Letteratura

Chong Han.; Stephen L. Buchwald. Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides. J. Am. Chem. Soc. 2009, 131 (22),7532-7533.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Dichiarazioni precauzionali: P223-P210-P231+P232-P260u-P201-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Obtain special instructions before use. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • A11498

    Ethyl cyanoacetate, 98+%
  • H58008

    Cyclopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58119

    n-Propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58121

    n-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58145

    Isobutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

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