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It is used in the preparation of P,N ligands for asymmetric Ir-catalyzed reactions.
Seung-Hoi Kim.; Reuben D. Rieke. 2-Pyridyl and 3-pyridylzinc bromides: direct preparation and coupling reaction. Tetrahedron. 2010, 66 (17),3135-3146.
Seung-Hoi Kim.; Reuben D. Rieke. A facile synthetic route for 2-pyridyl derivatives: direct preparation of a stable 2-pyridylzinc bromide and its copper-free and pd-catalyzed coupling reactions. Tetrahedron Lett. 2009, 50 (38),5329-5331.
Dichiarazioni di rischio (UE): H225-H261-H302-H333-H314-H318-H351-H335
Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.
Dichiarazioni precauzionali: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.