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171860-68-7 - Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58764 - Alfa Aesar

H58764 Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
171860-68-7
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 202,91
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Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671991

Proprietà chimiche

Formula
C5H9BrZn
Peso formula
214.41
Densità
0.955
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

It is an active nucleophile in Pd-catalyzed cross-coupling of heteroaryl halides.

Note

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Letteratura

Keith Biggadike.; Mohamed Boudjelal.; Margaret Clackers.; Diane M. Coe.; Derek A. Demaine.; George W. Hardy.; Davina Humphreys.; Graham G. A. Inglis.; Michael J. Johnston.; Haydn T. Jones.; David House.; Richard Loiseau.; Deborah Needham.; Philip A. Skone, Iain Uings.; Gemma Veitch.; Gordon G. Weingarten.; Iain M. McLay.; Simon J. F. Macdonald. Nonsteroidal Glucocorticoid Agonists: Tetrahydronaphthalenes with Alternative Steroidal A-Ring Mimetics Possessing Dissociated (Transrepression/Transactivation) Efficacy Selectivity. J. Med. Chem. 2007, 50 (26),6519-6534.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H314-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation.

Dichiarazioni precauzionali: P210-P231+P232-P260-P201-P261-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • H58852

    Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
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    2-Adamantylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58695

    2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58962

    3-Cyanopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

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