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7565-57-3 - Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58852 - Alfa Aesar

H58852 Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
7565-57-3
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 152,00
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Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671993

Proprietà chimiche

Formula
C6H11BrZn
Peso formula
228.44
Densità
0.963
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

It is used as primary and secondary intermediate.

Note

Store at room temperature. Incompatible with strong oxidizing agents and acids.

Letteratura

Maria F. Dalence-Guzmán.; Jörgen Toftered.; Viveca Thornqvist Oltner.; David Wensbo.; Martin H. Johansson. Synthesis of novel tetrahydroisoquinoline bronchodilators.Bioorg. Med. Chem. Lett. 2010, 20 (17),4999-5003.

Jie Wu , Yun Liao.; Zhen Yang. Synthesis of 4-Substituted Coumarins via the Palladium-Catalyzed Cross-Couplings of 4-Tosylcoumarins with Terminal Acetylenes and Organozinc Reagents.J. Org. Chem. 2001, 66 (10),3642-3645.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Dichiarazioni precauzionali: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2931.90
TSCA
No

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