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307531-83-5 - 2-(1,3-Dioxolan-2-yl)ethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58916 - Alfa Aesar

H58916 2-(1,3-Dioxolan-2-yl)ethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Codice CAS
307531-83-5
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
50ml 217,00
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2-(1,3-Dioxolan-2-yl)ethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD02260129

Proprietà chimiche

Formula
C5H9BrO2Zn
Peso formula
246.41
Densità
0.984
Sensibilità
Air Sensitive
Solubilità
Reacts with water.

Applicazioni

It is applied in pharmaceutical industry.

Note

Handle under dry protective gas. Keep away from strong oxidizing agents, heat, acid chlorides, bases and acids.

Letteratura

Zhe Lu.; Ashraf Wilsily.; Gregory C. Fu. Stereoconvergent Amine-Directed Alkyl-Alkyl Suzuki Reactions of Unactivated Secondary Alkyl Chlorides. J. Am. Chem. Soc. 2011, 133 (21),8154-8157.

Alexander J. Oelke.; Jianwei Sun.; Gregory C. Fu. Nickel-Catalyzed Enantioselective Cross-Couplings of Racemic Secondary Electrophiles That Bear an Oxygen Leaving Group. J. Am. Chem. Soc. 2012, 134 (6),2966-2969.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Dichiarazioni precauzionali: P223-P210-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
4.3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2932.99
TSCA
No

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