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35193-63-6 - 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99% - H60395 - Alfa Aesar

H60395 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%

Codice CAS
35193-63-6
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 17,70
5g 71,90
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1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%

MDL
MFCD00010045
EINECS
252-425-8

Proprietà chimiche

Formula
C20H13O4P
Peso formula
348.29
Solubilità
Extremely low soluble in water.

Applicazioni

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

Note

Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.

Letteratura

H Nakamura.; A Sano.; H Sumii. Chiral Separation of (R, S)-1, 1'-Binaphthyl-2, 2'-diyl Hydrogenphosphate by Capillary Electrophoresis Using Monosaccharides as Chiral Selectors. Analytical sciences. 199814 (2), 375-378.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni precauzionali: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2934.99
TSCA
No

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