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89878-14-8 - Diethyl(3-pyridyl)borane, 98% - 3-(Diethylboryl)pyridine - H64225 - Alfa Aesar

H64225 Diethyl(3-pyridyl)borane, 98%

Codice CAS
89878-14-8
Sinonimi
3-(Diethylboryl)pyridine

Dimensioni Prezzo ($) Quantità Disponibilità
5g 34,10
25g 136,00
100g 546,00
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Diethyl(3-pyridyl)borane, 98%

MDL
MFCD00012348

Proprietà chimiche

Formula
C9H14BN
Peso formula
147.03
Punto di fusione
172-175° lit.
Solubilità
Slightly soluble in water.

Applicazioni

Reactant for: preparation of inhibitors of ataxia telangiectasia mutated and Rad3 related (ATR) protein kinase as potential anticancer agents, N-Methylation reactions of the pyridyl group, Palladium catalyzed amination reactions, intramolecular Heck reactions, Coupling reactions and Synthesis of trisubstituted pyrimidines from polyhalopyrimidines via Suzuki coupling.

Note

Store in cool, dry place in tightly closed container. With adequate ventilation. Store away from oxidizing agent.

Letteratura

Minoru Ishikura; Tsukasa Ohta; Masanao Terashima. A Novel Synthesis of 4-Aryl-and 4-Heteroarylpyridines via Diethyl (4-pyridyl) borane. Chemical and Pharmaceutical Bulletin.1985 33(11), 4755-4763.

Antonio Guarna; Ernesto G. Occhiato; Fabrizio Machetti; and Vittoria Giacomellia.19-Nor-10-azasteroids. 5.1 A Synthetic Strategy for the Preparation of (+)-17-(3-Pyridyl)-(5β)-10-azaestra-1,16- dien-3-one, a Novel Potential Inhibitor for Human Cytochrome P45017α (17α-Hydroxylase/C17,20-lyase). J. Org. Chem. 1999 64(13),4985-4989.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P312a-P321-P332+P313-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
4381494
Codice tariffe armonizzato
2933.39
TSCA
No

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