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1865-01-6 - 4-Nitrophenyl formate, 98% - Formic acid 4-nitrophenyl ester - L00316 - Alfa Aesar

L00316 4-Nitrophenyl formate, 98%

Codice CAS
1865-01-6
Sinonimi
Formic acid 4-nitrophenyl ester

Dimensioni Prezzo ($) Quantità Disponibilità
5g 46,14
25g 147,60
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4-Nitrophenyl formate, 98%

MDL
MFCD00014713
EINECS
217-473-6

Proprietà chimiche

Formula
C7H5NO4
Peso formula
167.12
Punto di fusione
70-74°
Sensibilità
Moisture & Light Sensitive
Solubilità
Hydrolyzes in water. Soluble in dichloromethane.

Applicazioni

Convenient and selective reagent for the selective formylation of terminal amino groups in such basic amino acids as ornithine or lysine and formylation of α-amino groups in peptides.

Note

Moisture and light sensitive. Store away from water/moisture, oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store in dark. Store under inert gas. Protect from exposure to light.

Letteratura

Dimitrios Stefanidis, et al. Structure-reactivity correlations for reactions of substituted phenolate anions with acetate and formate esters.J. Am. Chem. Soc.,1993,115,(5), 1650-1656.

Satyendra Kumar, et al. Production, purification, and characterization of lipase from thermophilic and alkaliphilic Bacillus coagulans BTS-3.Protein Expression and Purification.,2005,41,(1), 38-44.

Convenient and selective reagent for the formylation of amino groups: Bull. Chem. Soc. Jpn., 36, 754 (1963); Synthesis, 979 (1982); Synth. Commun., 29, 1819 (1999).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
1950897
Codice tariffe armonizzato
2915.90
TSCA
Yes

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