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28460-01-7 - Diethyl methylthiomethylphosphonate, 97% - Methylthiomethylphosphonic acid diethyl ester - L00579 - Alfa Aesar

L00579 Diethyl methylthiomethylphosphonate, 97%

Codice CAS
28460-01-7
Sinonimi
Methylthiomethylphosphonic acid diethyl ester

Dimensioni Prezzo ($) Quantità Disponibilità
5g 60,30
25g 239,00
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Diethyl methylthiomethylphosphonate, 97%

MDL
MFCD00015131

Proprietà chimiche

Formula
C6H15O3PS
Peso formula
198.22
Punto di ebollizione
70-72°/0.2mm
Punto di infiammabilità
101°(213°F)
Densità
1.130
Indice di rifrazione
1.4660
Solubilità
It is insoluble in water.

Applicazioni

Diethyl methylthiomethylphosphonate, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. Diethyl(methylthiomethyl) phosphonate is a reactant for the synthesis of (+)-minfiensine via organocatalytic Diels-Alder/amine cyclization and 6-exo-dig radical cyclization. It is used in the preparation of fused nitrogen, sulfur, and phosphorus containing heterocyclic and relevant difurylpyridazine phosphonates with antimicrobial activity. It is also used as a reactant used in the preparation of fused heterocyclic.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

Letteratura

EJ Corey.; JI Shulman. Application of lithium reagents from (1-methylthio) alkylphosphonate esters to the synthesis of ketones. The Journal of Organic Chemistry. 197035,(3) , 777-780.

J Motoyoshiya.; Y Hongo.; H Tanaka. A Convenient Synthesis of 1, 4-Diketones. Synthetic Communications. . 199121,(8-9) , 997-1000.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319

Causes skin irritation. Causes serious eye irritation.

Dichiarazioni precauzionali: P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313

Wear protective gloves and eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists:

Altri riferimenti

Beilstein
1705833
Codice tariffe armonizzato
2931.39
TSCA
No

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