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513-81-5 - 2,3-Dimethyl-1,3-butadiene, 98%, stab. with 100ppm BHT - L04207 - Alfa Aesar

L04207 2,3-Dimethyl-1,3-butadiene, 98%, stab. with 100ppm BHT

CAS Number
513-81-5
Synonyms

Size Price ($) Quantity Availability
10g 42,70
50g 114,00
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2,3-Dimethyl-1,3-butadiene, 98%, stab. with 100ppm BHT

MDL
MFCD00008595
EINECS
208-172-0

Chemical Properties

Formula
C6H10
Formula Weight
82.15
Melting point
-76°
Boiling Point
68-69°
Flash Point
-1°(30°F)
Density
0.726
Refractive Index
1.4380
Solubility
Miscible with chloroform. Immiscible with water.

Applications

2,3-Dimethyl-1,3-butadiene undergoes Diels Alder cycloaddition reaction and it also participates in polymerization reactions. It is also involved in manufacturing of synthetic rubber.

Notes

Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

For examples of use in Diels-Alder reactions, see: Org. Synth. Coll., 3, 310 (1955); 7, 4 (1990). For an asymmetric Diels-Alder reaction catalyzed by a chiral acyloxyborane, see: Org. Synth. Coll., 9, 722 (1998).

For use in phosphole synthesis, see Dichlorophenyl­phosphine, A10284.

/n

Uemura, T.; Nakanishi, R.; Mochizuki, S.; Murata,Y.; Kitagawa, S. Radical polymerization of 2,3-dimethyl-1,3-butadiene in coordination nanochannels. Chem. Commun. 2015, 51 (48), 9892-9895.

Nakashim, E.; Yamamoto, H. Continuous flow of nitroso Diels-Alder reaction. Chem. Commun. 2015, 51 (61), 12309-12312.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H304

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways.

Precautionary Statements: P210-P280-P240-P241-P233-P301+P310-P303+P361+P353-P405-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,3238
Beilstein
605285
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2901.29
TSCA
Yes

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